Recycled ABS Polymer Doped with Outdated Lansoprazole as a Corrosion Protection Composite Coating for Mild Steel in Chloride Solution

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  •   Sandra Viveros, Ph. D. Student

  •   Carmina Menchaca, Dr.

  •   Miguel A. Hernandez, Dr.

  •   Alba Covelo, Dr.

  •   Jorge Uruchurtu

Abstract

Acrylonitrile-butadiene-styrene (ABS) is a common waste polymer by-product from industry. Outdated medicines are usually discarded and could be a valuable asset for other applications such as metallic corrosion inhibition. The aims of the present work is to manufacture a recycled ABS polymer doped with outdated lansoprazole medicament as a corrosion protection composite coating. It was applied to mild steel and immersed in chloride solution, and evaluate its possible corrosion protection properties using different electrochemical techniques. The manufactured coating presents good corrosion protection properties showing an 80% efficiency as a function of time of immersion in the aggressive solution.


Keywords: Corrosion, ABS, Lansoprazole, Composite Coating, Steel, Chlorides

References

N. Agrawal, D. Campbell, M. Safdi, N. Lukasik, B. Huang, and M. Haber, ¨Superiority of lansoprazole vs. ranitidine in healing non-steroidal anti-inflammatory drug-associated gastric ulcers: results of a double-blind, randomized, multicenter study. NSAID-Associated Gastric Ulcer Study Group¨. Archives of Internal Medicine, Vol.160, 10, pp.1455–1461. 2000.

B. D. Mert, M.E. Mert, G. Kardas and B.Yazıcı. ¨Experimental and theoretical investigation of 3-amino-1,2,4-triazole-5-thiol as a corrosion inhibitor for carbon steel in HCl medium¨. Corros. Sci., Vol. 53, pp. 4265–4272, 2011.

M Palomar-Pardavé, M. Romero-Romo, ¨H. Herrera-Hernández, M. A. Abreu-Quijano, N. V. Likhanova, J. Uruchurtu and J. M. Juarez-Garcia¨, Influence of the alkyl chain length of 2 amino 5 alkyl 1,3,4 thiadiazole compounds on the corrosion inhibition of steel immersed in sulfuric acid solutions, Corros. Sci., Vol. 54, 1, pp. 231-243, 2012.

V. Bustos-Terrones, J. Uruchurtu, J. J. Rochín-Medina, K. Ramírez, J. G. Rangel-Peraza, M. A. Romero-Romo and Y. Bustos-Terrones. ¨Synthesis, characterisation and electrochemical evaluation of a functionalised coating for mild steel corrosion protection¨, Surface Eng., Vol. 35, 4, pp. 360-369, 2019.

J. Uruchurtu Chavarin, ¨Electrochemical Investigations of the Activation Mechanism of Aluminum¨, Corrosion. Vol. 47, 6, pp. 472-479, 1991.

M. Hernández-Escampa, F. Rodríguez-Acuña, F. Millán-Cruz, P. Rodríguez-Rojas, M. A. Hernández-Gallegos, A. Covelo, C. Menchaca-Campos, and Jorge Uruchurtu, ¨Electrochemical Evaluation of a Recycled Copolymer Coating for Cultural Heritage Conservation Purposes¨ Int. J. Polymer Sci., Vol. 2013, pp.1-9, 2013.

V.Bustos, L. Concha, C. Menchaca-Campos, J. Uruchurtu, M. A. Romero, M. Esparza, A. Covelo, M. A. Hernandez and E. Sarmiento, ¨Eco-Friendly Recycled Pharmaceutical Inhibitor/ Waste Particle Containing Hybrid Coatings for Corrosion Protection, Chapter 10, Biobased and Environmental Benign Coatings, Wiley, 2016.

J. Uruchurtu-Chavarin and J. M. Malo, “Electrochemical noise as a powerful electrochemical technique for corrosion studies,” Trends in Corrosion Research, Vol. 2, pp. 49–58, 1997.

R. Cottis, and S. Turgoose. "Electrochemical impedance and noise, corrosion testing made easy.", Ed. B. C. Syrett, NACE International, Houston, 1999.

R. Krache and I. Debbah, “Some mechanical and thermal properties of PC/ABS blends,” Mat. Sciences and Appl., Vol. 2, 5, pp. 404–410, 2010.

ASTM D3359 Standard, ¨Test Methods for Rating Adhesion by Tape Test¨. ASTM International, West Conshohocken, PA, 2017.

M. Robinson, and J. Horn. ¨Clinical Pharmacology of Proton Pump Inhibitors. What the Practising Physician needs to know¨. Drugs. Vol. 63, pp. 2739-54, 2003.

H. J. Flitt and D. P. Schweinsberg. ¨Evaluation of corrosion rate from polarisation curves not exhibiting a Tafel region¨. Corros. Sci. Vol. 47, pp. 3034–3052, 2005.

G. Gece. ¨Drugs: A review of promising novel corrosion inhibitor¨. Corros. Sci., Vol. 53, pp. 3873–3898, 2011.

N. Vaszilcsina, V. Ordodib and A. Borzaa. ¨Corrosion inhibitors from expired drugs¨, Int. J. of Pharmaceutics. Vol. 431, pp. 241– 244, 2012.

J.N Murray and H.P. Hack. ¨Long-term testing of epoxy-coated steel in ASTM seawater using electrochemical impedance spectroscopy¨. Corrosion, Vol. 47, 6, pp. 480-489, 1991.

F. Mansfeld, and M. W., Kendig, ¨Determination of the polarization resistance form impedance measurements¨, Werkstoffe und Corrosion, Vol. 34: pp. 397-401, 1983.

M. Hernandez, J. Genesca, J. Uruchurtu, F. Galliano and D. Landolt, ¨Effect of an inhibitive pigment zinc-aluminum-phosphate (ZAP) on the corrosion mechanisms of steel in waterborne coatings¨, Prog. in Org. Coatings, Vol. 56, 2-3, pp. 199-206, 2006.

E. Ituen, O. Akaranta and A. James. ¨Evaluation of Performance of Corrosion Inhibitors using Adsorption Isotherm Models: An Overview¨. Chem. Sci. Int. J., Vol. 18, 1, pp. 1-34, 2017.

M. Y. Díaz-Cardenas, M. G. Valladares-Cisneros, C. Menchaca-Campos, S. Lagunas-Rivera, J. G. Gonzalez-Rodríguez1, J. Uruchurtu-Chavarín, Electrochemical and chemical quantum studies of a natural alkaloid compound: Boldine, as green corrosion behaviour on carbon steel and Copper in sulfuric acid, J. Mater. Environ. Sci., 2019, 10(10), pp. 1011-1024.

A. Carmona-Hernandez, E. Vazquez-Velez, J. Uruchurtu-Chavarin, J. G. Gonzalez-Rodriguez and L. Martinez-Gomez, ¨Use of an imidazol synthetized from palm oil as a corrosion inhibitor for a supermartensitic stainless steel in H2S¨, Green Chem. Lett. and Reviews, Vol. 12, 1, pp. 89-99, 2019.

M. G. Wyzgoski, “Effects of oven aging on ABS, poly (acrylo- nitrile-butadiene-styrene),” Polymer Eng. and Sci., Vol. 16, 4, pp. 265–269, 1976.

C. Monticelli, A. Frignani and G. Trabanelli. ¨Corrosion inhibition of steel in chloride-containing alkaline solutions¨. J. of Appl. Electrochem., Vol. 32, pp. 527–535, 2002.

R. Selvaraj, M. Selvaraj and S.V.K. Iyer. ¨Studies on the evaluation of the performance of organic coatings used for the prevention of corrosion of steel rebars in concrete structures¨. Progr. in Org. Coat., Vol. 64, pp. 454–459, 2009.

D. Thirumoolan, T. Siva, K. Vetrivel, S. Sathiyanarayanan, K. Anver Bashaa. ¨Corrosion resistant performance of hydrophobic poly(N-vinyl imidazole-co-ethyl methacrylate) coating on mild steel¨. Progr. in Org. Coat., Vol. 89, pp.181–191, 2015.

C. López-Meléndez, R.G. Bautista-Margulis, E. M Garcia-Ochoa, H. E. Esparza-Ponce, C. Carreño-Gallardo, C. Gaona-Tiburcio, J. Uruchurtu-Chavarín and A. Martínez-Villafañe, ¨Evaluation of Corrosion Resistance of Thin Films 304 Stainless Steel Deposited by Sputtering¨. Int. J. Electrochem. Sci., Vol. 7, pp. 1149-1159, 2012.

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How to Cite
[1]
Viveros, S., Menchaca, C., Hernandez, M., Covelo, A. and Uruchurtu, J. 2020. Recycled ABS Polymer Doped with Outdated Lansoprazole as a Corrosion Protection Composite Coating for Mild Steel in Chloride Solution. European Journal of Engineering and Technology Research. 5, 4 (Apr. 2020), 429-435. DOI:https://doi.org/10.24018/ejers.2020.5.4.1874.